Date Log
Daya Jerap dan Efisiensi Adsorpsi Ion Tembaga Menggunakan Biosorben Serat Daun Nanas (Ananas comosus)
Corresponding Author(s) : Nurfatihayati Nurfatihayati
Journal of Bioprocess, Chemical and Environmental Engineering Science,
Vol 4 No 2 (2023): Journal of Bioprocess, Chemical, and Environmental Engineering
Abstract
One of the essential heavy metals that living things require in small amounts is the copper ion (Cu2+). However, the presence of dissolved copper metal is toxic to organisms and can pollute the environment if it exceeds a predetermined threshold value. Pineapple leaf waste with high cellulose content can be used as a copper ion biosorbent. This research studied the effect of pineapple leaf fiber particle size and contact time at the adsorption of copper ions on the adsorption capacity and effectiveness of pineapple leaf fiber biosorbents in adsorbing copper ions. The research began with cleaning, drying, and grinding pineapple leaves. Then, the activation process was carried out for 70 minutes using 9% NaOH. The adsorption process of copper ions was carried out using 1 g of pineapple leaf fiber biosorbent based on the varying sizes of the biosorbent particles size of the biosorbent -40/+60; -60/+80; and -80/+100 mesh and contact time 30; 60; 90; and 120 minutes at a stirring speed of 90 rpm and a concentration of 10 ppm copper ion adsorbate to measure the remaining copper ions in solution after the adsorption process. The activated pineapple leaf fiber biosorbent has a water content of 14.3%; 12.4%; and 11.2% for each biosorbent particle size -40/+60; -60/+80; and -80/+100 meshes. The highest adsorption effectiveness was 94.93%, which occurred at a contact time of 90 minutes with a biosorbent particle size of -80/+100 mesh and an adsorption value of 0.94 mg/g.
Keywords
Download Citation
Endnote/Zotero/Mendeley (RIS)BibTeX
References
Cahyani, M.D., Azizah, R., & Yulianto, B. (2012). Studi Kandungan Logam Berat Tembaga (Cu) pada Air, Sedimen, dan Kerang Darah (Anadara granosa) di Perairan Sungai Sayung dan Sungai Gonjol, Kecamatan Sayung, Kabupaten Demak. Journal of Marine Research, 1(2), 73-79.
Cheraghi, E., Ameri, E., & Moheb, A. (2015). Adsorption of Cadmium Ions from Aqueous Solutions Using Sesame as a Low-Cost Biosorbent: Kinetics and Equilibrium Studies. International Journal of Environmental Science and Technology., 12(8), 2579-2592.
Handayani, A.W. (2010). Penggunaan Selulosa Daun Nenas sebagai Adsorben Logam Berat Cd (II). Skripsi. Fakultas Matematika dan Ilmu Pengetahuan Alam, Universitas Sebelas Maret, Surakarta.
Hidayat, P. (2008). Teknologi Pemanfaatan Serat Daun Nanas sebagai Alternatif Bahan Baku Tekstil. Teknoin., 13(5), 31-35.
Keon, D.Y., Yulianti, I.M., & Jati, W.N. (2018). Kemampuan Selulosa Daun Mahkota Nanas (Ananas comosus) sebagai Biosorben Logam Tembaga (Cu). Biota., 3(2), 70-78. https://doi.org/10.24002/biota.v3i2.1895
Keputusan Menteri Negara Lingkungan Hidup. Nomor 51 Tahun 2004. Baku Mutu Air Laut.
Khoirunnisa, A., & Senam, S. (2017). Pengaruh Interfensi Ion Cadmium (Cd2+) terhadap Biosorpsi Ion Timbal (Pb2+) oleh Sel Ragi Saccharomyces cerevisiae. Jurnal Kimia Dasar., 6(2): 53-58.
Kusuma, G.D.P., Made, W., & Gusti, L.W. (2014). Isoterm Adsorpsi Cu2+ oleh Biomassa Rumput Laut Eucheuma spinosum. e-Journal Kimia Visvitalis Universitas Pendidikan Ganesha., 2(1): 1-8.
Laos, L.E., & Arkilaus, S. (2016). Pemanfaatan Kulit Singkong sebagai Bahan Baku Karbon Aktif. Jurnal Ilmu Pendidikan Fisika., 1(1): 32-36.
Linda, A. (2011). Pemanfaatan Rumput Laut Sargassum sp sebagai Adsorben Limbah Cair Industri Rumah Tangga Perikanan. Skripsi., Departemen Teknologi Hasil Perairan, Institut Pertanian Bogor.
Mayangsari, N.E., & Ulvi, P.A. (2021). Model Kinetika Adsorpsi Logam Berat Cu2+ menggunakan Selulosa Daun Nanas. Jurnal Chemurgy., 5(1), 15-21.
Mayangsari, N.E., Apriani, M., & Veptiyan, E.D. (2019). Pemanfaatan Limbah Daun Nanas (Ananas comosus) sebagai Adsorben Logam Berat Cu. Journal of Research and Technology., 5(2), 129-138.
Naimah, S., & Ermawati, R. (2011). Biosorpsi Logam Berat Cr (VI) dari Limbah Industri Pelapisan Logam Menggunakan Biomassa Saccharomyces cerevisiae dari Hasil Samping Fermentasi Bir. Jurnal Kimia dan Kemasan., 33(1), 113-117. http://dx.doi.org/10.24817/jkk.v33i1.1837
Peraturan Menteri Kesehatan Republik Indonesia. (2010). Nomor: 492/MENKES/PER/IV/2010, Persyaratan Kualitas Air Minum.
Phuengpai, P., Singjanusong, T., Kheangkhun, N., & Wattanakornsiri, A. (2021). Removal of Copper (II) from Aqueous Solution Using Chemically Modified Fruit Peels as Efficient Low-Cost Biosorbents. Water Science and Engineering., 14(4), 286-294. https://doi.org/10.1016/j.wse.2021.08.003
Said, N.I. (2010). Metode Penghilangan Logam Berat (As, Cd, Cr, Ag, Cu, Pb, Ni dan Zn) di dalam Air Limbah Industri. Jurnal Air Indonesia, 6(2), 136-148.
Setiaka, J., Ita, U., & Nurul, W. (2010). Adsorpsi Ion Logam Cu (II) dalam Larutan pada Abu Dasar Batu Bara Menggunakan Metode Kolom. Prosiding Skripsi Semester Genap 2010/2011., Institut Teknologi Sepuluh November, Surabaya.
Setiawan, A., Afiuddin, A.E., Aini, Q., & Dewi, T.A. (2018). Recovery Koagulan dari Sludge WWTP Pembangkit Listrik Tenaga Uap sebagai Alternatif Pengolahan Air Limbah secara Kimia. Jurnal Riset Teknologi Industri., 12(2), 126-138.
Setiawan, A., Basyiruddin, F., & Dermawan, D. (2019). Biosorpsi Logam Berat Cu (II) Menggunakan Limbah Saccharomyces cerevisiae. Jurnal Presipitasi., 16(1): 29-35. https://doi.org/10.14710/presipitasi.v16i1.29-35
Sukir. (2008). Pembuatan dan Karakterisasi Karbon Aktif dari Sekam Padi. Tesis., Institut Teknologi Bandung.
Wenten, I.G., Aryanti., & Khoiruddin. (2014). Teknologi Membran dalam Pengolahan Limbah. Diktat Teknik Kimia., Institut Teknologi Bandung.
Yuniwati, M. (2012). Produksi Minyak Biji Kapuk dalam Usaha Pemanfaatan Biji Kapuk sebagai Sumber Bahan Nabati. Jurnal Teknologi Technoscientia., 4(2), 203-211.